Physical Chemistry Seminar Series
Department of Chemistry, UNC Chapel Hill
Spring 2021
[click here to request a meeting with our speaker]
Time and date: January 27, 11:15 am eastern time.
Speaker: Eric Potma, University of California, Irvine
Title: Nanospectroscopy through force
Abstract: Imaging with molecular contrast at the nanoscale is important for a myriad of applications, yet it remains a technical challenge. Over the past two decades, various flavors of optical spectroscopy combined with atomic force microscopy have been developed, each offering hope for a more routine nanospectroscopy technology. One of these approaches is photo-induced force microscopy (PiFM), a non-contact scan probe technique that is sensitive to the light-induced polarization in the material. PiFM has been used to generate molecular maps with 5 nm resolution, based on absorption contrast or on contrast derived from nonlinear optical interactions. Nonetheless, questions remain about the origin of the signal, in particular the possible contribution of forces that result from the thermal expansion of the sample. In this presentation, we will discuss various physical mechanisms that contribute to the PiFM signal and highlight several applications that are unique to the PiFM technique.